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Study on AB3-Type Hydrogen Storage Composite Alloys
Author: LiuShuXia
Tutor: ZhaoZuo
School: Changchun University of Science and Technology
Course: Inorganic Chemistry
Keywords: Of AB3 type of hydrogen storage alloys Physical diffusion method Heat treatment method Electrochemical properties
CLC: TG139.7
Type: Master's thesis
Year: 2011
Downloads: 26
Quote: 0
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Abstract
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RE-Mg-Ni the AB3 type hydrogen storage alloy i.e. magnesium based hydrogen storage alloy , its synthesis process , both containing a large number of the CaCu5 structure of the AB5 type alloy component , also containing PuNi3 constructed AB3 type alloy component , both in the synthesis process constitutes a complex phase structure ; the structure corrosion potential difference, and magnesium in the dominant electrolyte instability , easily lead to the capacity of the multiplexed phase hydrogen storage alloy attenuation speed , self-discharge rate . The heat treatment process on the composite structure and its preparation have a significant impact , especially in terms of the number of the the CaCu5 and PuNi3 structure and its phase transition temperature relationship . In this study, by infiltration lithium super entropy method to address the problem , study the preparation and performance of complex phase AB3 -type hydrogen storage alloy . The selected to La0.7Mg0.3Ni2.8Co0.5 system , through physical diffusion method , magnesium - lithium intermediate alloys and their composites its processing and to study its electrochemical properties . The results show that the magnesium - Add lithium intermediate alloy significantly improved the cycle stability and the maximum discharge capacity of the hydrogen absorbing alloy , but decrease in the discharge capacity of magnification ; with molten salt seepage lithium technology based on this system containing lithium ultra entropy synthesis and electrochemical properties of the alloy . In addition, the study the AB4.7 type hydrogen storage alloys under different temperatures , different heat treatment composition and electrochemical properties . The results show that , increase the discharge capacity of the lithium content is gradually increased , at the same time can improve the the alloy charge retention rate to improve the performance of high and low temperature discharge ; maximum discharge capacity of the alloy after annealing , charge retention rate discharge performance , and electrochemical properties overall showed a downward trend.
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CLC: > Industrial Technology > Metallurgy and Metal Craft > Metallurgy and Heat Treatment > The alloy learn with a variety of properties of alloys > Other special nature of the alloy > Hydrogen storage alloy
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