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Preparation and Properties of Rare Earth Ions-doped Oxide Luminescence Nanomaterials

Author: BaiHaiYing
Tutor: LiuGuiXia
School: Changchun University of Science and Technology
Course: Inorganic Chemistry
Keywords: Homogeneous precipitation method Hydrothermal method Sol - gel method . Core-shell Nano Luminescent Materials Rare earth oxides Surface effect Concentration quenching
CLC: TB383.1
Type: Master's thesis
Year: 2011
Downloads: 78
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Abstract


Rare earth luminescent materials in the flat panel display has a wide range of applications in the field of green lighting, optical communications and laser devices. The rare earth oxides are excellent host material;, rare earth doped nanostructured luminescent material surface coated with a layer of undoped matrix material to reduce surface defects, has improved to a certain extent the luminescent properties of nanomaterials. In this paper, the homogeneous precipitation method, different morphology of the oxide luminescent materials and surface coated matrix of light-emitting materials were prepared by hydrothermal method and sol - gel method. Get some meaningful results: 1. Homogeneous precipitation method successfully synthesized uniform spherical Gd2O3: of Eu3 light-emitting materials and different shell thickness Gd2O3: core - shell structure of Eu3 @ Y2O3 luminescent materials, key research Gd2O3: Eu3 surface coated with different thickness of the matrix Y203 impact on the luminescence properties, and found that when the nucleation layer and the shell thickness ratio R = the luminous intensity ratio of 4:1, the uncoated - Gd2O3: Eu3 enhancement that nuclear - The shell samples lowering nano Gd2O3: the negative impact of Eu3 surface effect to the luminous intensity. By homogeneous precipitation method successfully synthesized the the different Eu3 doping concentration of Y2O3 of spherical: of Eu3 light-emitting materials and different doping concentration Y203: Eu3 @ Gd203 core-shell structure of the light-emitting materials. The fluorescence spectra: of Y2O3: of Eu3 spherical particle surface coating matrix Gd2O3, luminous intensity than the uncoated of Y2O3: Eu3 enhance luminous intensity difference of the core-shell structure particles and single particle quenching concentration of Eu3 ions. . Hydrothermal Synthesis of spherical YVO4: Eu3 light-emitting materials and coated matrix material GdVO4 with the law on its surface, the formation of a core-shell structure of YVO4: of Eu3 _AT_ the GdVO4 luminous Materials. The fluorescence spectra of YVO4: Eu3 surface coated GdVO4 after the emission intensity than the uncoated YVO4: Eu3 Zeng Qiang. 4 (1) by the sol - gel prepared by a smooth surface GdVO4: of Eu3 particles as well as the core-shell structure GdVO4: Eu3 @ GdVO4 light-emitting materials. Before coating diameter of about 310nm, the thickness of the cladding layer is approximately 45nm. (2) by hydrothermal method to prepare a sandwich structure of GdVO4: of Eu3 well as core-shell structure GdVO4: Eu3 @ YVO4 light-emitting material, coated prior to a diameter of about 310nm thickness of about 110nm. The cladding layer having a thickness of 10nm. The fluorescence spectra showed that: the core-shell structure prepared by the above two methods GdVO4: of Eu3 _AT_ LnVO4 (Ln = Gd, Y) luminous intensity than the uncoated enhanced.

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