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Synthesis, Structures and Characterization of Novel Porous Metal-Organic Carboxylate Frameworks

Author: SunFuXing
Tutor: ZhuGuangShan
School: Jilin University
Course: Inorganic Chemistry
Keywords: Porous material Metal organic framework compounds Crystal structure Topology Gas adsorption Liquid adsorption Fluorescence Magnetic Stability
CLC: O621.2
Type: PhD thesis
Year: 2010
Downloads: 797
Quote: 2
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Abstract


This thesis is based on the crystal engineering principles , from the application of the porous material and functional way , committed to the application of metal organic framework compounds designed synthetic strategy , research porous metal organic framework law of the synthesis , as well as multi-functional in nature. In this thesis, a carboxylic acid ligands in metal organic framework Synthesis and properties of study to the progressive realization of the metal organic framework compounds semi-directional and directional synthesis is the main purpose. In this paper the different characteristics of selected organic ligands synthesized sixteen metal organic framework compounds and to study the nature of these materials , and magneto-optical holes and other aspects of performance. These findings include: the use of low symmetry of the three organic carboxylic acid ligands node constructed with a single hand of a pore structure, and a non-cardiac LiGe two isomorphic compounds topology ; 4,4 ' - United pyridine success of the ( 6,3 ) pillared layered structure into a two-dimensional and three-dimensional double-layer open framework ; using fluorinated carboxylic acid ligand and a transition metal to build a six stable metal organic framework compounds ; two novel successfully by manganese , cobalt and HKUST-1 constructed isomorphic compounds; nitrogen-containing ligand pcu topology constructed a compound having the ligand in the reaction occurred during the oxidation reaction . This paper describes in detail the synthesis of the above conditions , structure, and stability , optical, magnetic , adsorption properties . In the rich metal organic framework synthetic chemical compounds and structural chemistry at the same time , the class oriented synthesis and properties of materials developed and accumulated valuable experimental fact.

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CLC: > Mathematical sciences and chemical > Chemistry > Organic Chemistry > Organic Chemistry general issues > Properties of organic compounds
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