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Study on Red Fluorescent Material of M-Al-Si-N
Author: MenKai
Tutor: BaiChaoZuo
School: Changchun University of Science and Technology
Course: Materials Physics and Chemistry
Keywords: rare earths luminescence nitride phosphor CaAlSiN3:Eu2+
CLC: O611.3
Type: Master's thesis
Year: 2012
Downloads: 73
Quote: 0
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Abstract
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In this thesis, the CaAlSiNa:Eu2+red phosphor and solid solutions are prepared by the carbothermal reduction and nitridation. The phosphor are analyzed by X-ray powder diffraction and fluorescence spectrophotometer for researching the crystal structure and the spectral characteristics. The results show that the best sintering temperature for synthesising phosphor is1600℃, constant temperature for6hours, the best ventilation of nitrogen is4L/min, the best doping concentration of Eu2+is20mo1%, the best doping concentration of NH4CI is0.6wt%, the best doping ratio for nc/nca is1.8. the CaAlSiNs:Eu2+phosphor belongs to orthorhombic phase, when it is stimulated by blu-ray at450nm, its emission peak locates at640nm, which has a broadband form570nm to700nm. In addition, its excitation peak locates at460-480nm. When the doping concentration of Eu2+increases, the emission intensity increased gradually; When the doping concentration of Eu2+greater than20mol%, the emission intensity began to decrease.
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CLC: > Mathematical sciences and chemical > Chemistry > Inorganic Chemistry > Chemical elements and inorganic compounds > Nature
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