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Alicyclic class carboxyl hydroxamic acid compounds synthesized collector performance study
Author: YiYunLai
Tutor: JiangYuRen
School: Central South University
Course: Organic Chemistry
Keywords: Carboxyl hydroxamic acid Collector A diaspore Aluminosilicate minerals Adsorption mechanism
CLC: TD923.13
Type: Master's thesis
Year: 2010
Downloads: 75
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Abstract
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Development of low-grade bauxite efficient positive flotation to improve one of our diaspore bauxite aluminum-silicon ratio (A / S), is of great significance to solve the problems existing in China 's alumina production . Carboxyl hydroxamic acid collector alicyclic group Synthesis and made ??a systematic study of a boehmite , kaolinite and illite flotation performance , and by the amount of adsorption measurements , Zeta potential measurement and infrared spectroscopy , etc. means to explore the mechanism of action of the collector with a diaspore and aluminosilicate minerals . Hydroxylamine hydrochloride with the corresponding ester as the main materials MCTB , and CETB two kinds of collectors , and their structures were characterized by means of infrared spectroscopy and elemental analysis . Single mineral flotation experimental results show that the collector MCTB, CETB at a concentration of 2 × 10- 4M , a diaspore flotation pH 6-7 , a recovery rate of diaspore 90.2% and 72.8% ; the while MCTB the CETB recoveries of kaolinite and illite are low , less than 36.1% , showed that MCTB are superior selectivity and collector of CETB . The use MCTB further separation of the artificial mixed ore and mineral flotation . Experimental results show that at pH = 6.3 , the the collecting agent MCTB concentration of 6.0 × 10-4M-8.0 × 10-4M , a diaspore and aluminum silicate minerals separation can be achieved . MCTB is expected to become a new type of chelating bauxite collector . Zeta potential measurement results show that the dynamic potential of the collector of a diaspore greater impact , while a relatively small impact on the dynamic potential of kaolinite and illite ; mineral particles by scanning electron microscopy (SEM) images (× 20,000) shows that the mineral particles appearance , surface structure flotability is essential. The adsorption amount of experimental results show that , MCTB in a diaspore surface adsorption is much larger than the amount of kaolinite , illite surface adsorption , consistent with the order of the single mineral flotation recoveries . Infrared spectroscopy further evidence collector in a diaspore surface -COOH and -CONHOH the aluminum ion chemistry of the mineral surface into a key role in kaolinite , illite surface to produce hydrogen role.
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CLC: > Industrial Technology > Mining Engineering > Beneficiation > Beneficiation processes and methods > Planktonic dressing > Flotation reagent > Trapping agent
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