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Effect of Ti Content on Tribological and Thermal Impact Properties of CrTiAlN Coatings by Magnetron Sputtering
Author: ZuoKe
Tutor: JiangBaiLing;BaiLiJing
School: Xi'an University of Technology
Course: Materials Science and Engineering
Keywords: CrTiAlN coating phase microstructure tribological property thermal impact property
CLC: TG174.4
Type: Master's thesis
Year: 2009
Downloads: 13
Quote: 0
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Abstract
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CrTiAIN coatings with different Ti content were deposited on high speed steel and silicon wafers substrates by changing Ti target current in magnetron sputtering system. The chemical composition, phases and microstructures of the coatings were analyzed by EDS, XRD, SEM and TEM. The basic mechanical properties such as hardness, toughness, adhesion strength and impact properties of the coatings were tested. Friction and wear behavior of the coatings were studied by WMM-2 wear tester and optical microscope. The thermal impact properties of the coatings were evaluated using box electrical resistance furnace at different temperature. Then Mechanisms which Ti content effect on tribological adaptability and thermal impact properties of the coatings were discussed through combining with the chemical composition, phases, microstructures and basic mechanical properties of the coatings.The results indicate:With the increase of Ti content, the (Cr,Ti,Al)N system gradually substitutes for CrN and becomes mainly phases of the coatings, besides it appears a small quantity of TiN phase in the coatings, the surface morphology of the coatings gradually changes from triangular pyramid structure to cellular structure. Coating with 5.13at% Ti content shows the best mechanical properties. Friction and wear at room temperature, with the increase of Ti content, the friction coefficients with 45 steel take from 0.5 to 0.37, wear rates of the coatings also decrease, and the wear mechanism undergoes a adhesive wear→abrasive wear transformation. Heat friction and wear, with the increase of Ti content, the friction coefficients decrease. Wear rate of the coating with 0% Ti content is largest, the coating with the most Ti content show larger than wear rate of the other coatings. Adhesive wear, abrasive wear and oxidation wear are three most factor that is effect on the heat wear mechanism, and with the increase of Ti content, oxidation wear become dominant in three kinds wear mechanism. With the increase of Ti content, CrTiAIN coatings have different thermal impact properties. As for coating with high Ti content, TiO2 that is loosen structure was easily formed when happen thermal impact, it offer the chance of further oxidation for coatings and reduce thermal impact property of the coatings. Finally, the coatings with high Ti content have the worse thermal impact property.
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CLC: > Industrial Technology > Metallurgy and Metal Craft > Metallurgy and Heat Treatment > Metal corrosion protection,metal surface treatment > Corrosion control and protection > Metal surface protection technology
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