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Study on the Preparation and Application of Microcapsule by in-situ Polymerization
Author: WangKaiHui
Tutor: ZhouXiaoDong
School: East China University of Science and Technology
Course: Chemical Engineering
Keywords: microcapsule surface active agent damping magnetism
CLC: TB383.4
Type: Master's thesis
Year: 2012
Downloads: 21
Quote: 0
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Abstract
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Urea-formaldehyde Microcapsules are widely researched in many fields due to their excellent sealing property, mechanical property, etc. A series of microcapsules were prepared by in situ polymerization with different concentration of surfactant EMA. After the effects of various result parameters were experimentally investigated, the mechanism of urea-formaldehyde microcapsules prepared by one-step process was studied. And then we prepared some microcapsules with special functional properties. The main contents are listed as follows:After a series of microcapsules were prepared in different concentration of the poly(ethylene-alt-maleic anhydride) (EMA), we made some research on the surface morphology, the shell thickness, the reaction mechanism etc, of the microcapsules. Results showed that the concentration of the EMA was important for the dispersibility of the microcapsules when they were dried, microcapsules with good dispersibility and special structure formed only if the concentration of poly(E-MA) kept below a special value. At the same time it was found that the concentration required for the best release property of the microcapsules wall was the same as critical micelle concentration (CMC) of EMA.Tetrachroloethylene (TCE) and ferroferric oxide which were prepared by ourselves were chosen as core materials, we prepared some microcapsules with absorb microwave property. The effect of the microcapsule particle content, diameter, were researched on the property of damping and microwave absorb. The results showed that the attenuation reflection peak of the composite materials increased nearly 100% in the magnetic field when the volume of microcapsule content was 20%, at the same time, the composite material loss factor reached 0.3. In the fixed frequency 1 Hz conditions, the smaller of microcapsule particle size,composite materials in the glass transition temperature of the peak value is higher.Depend on the different volatility of TCE and olive oil, we use that material make some microcapsules with special structure. The application prospect in water sound absorption was prospect after the damping properties were researched.
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