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Hydrogen as a clean, efficient, safe, sustainable energy, be regarded as the most potential for development of clean energy of the 21st century, the human development direction of the energy strategy. Hydrogen energy system, including hydrogen production, storage, transportation and application of the three links, and hydrogen storage is the key, is the major technical barriers to hydrogen energy applications. With the large number of discovered gas hydrates in the global the hydrate gas storage technology has become a research focus in the field of energy and resources in the field of hydrate hydrogen storage has become possible, and is currently in the research stage. From both thermodynamic and kinetic studies of gas hydrate, and provide technical support for research hydrate hydrogen storage. First study the TBAB-CH4 binary hydrate maglev the weight adsorbed instrument in the generation of a new method of measuring the hydrate density and volume of gas - magnetic suspension balance weighing method. Experiment measured the binary hydrate density ranged between 0.972 ~ 1.082 g · cm-3. The mass fraction of 20.8 wt% TBAB solution, 3.01 ~ 7.07 MPa within the same pressure, the temperature is 273.64 K, hydrate is generated gas is greater than the volume of gas hydrate in the other experimental temperature, and the pressure at 5.05 MPa hydrated The matter of the volume of gas 55.73 V / V, to exceed the TBAB-CH4 binary hydrate ideal gas storage capacity of 45.12 V / V. Secondly, the dry water - methane hydrate, an accelerated gas hydrate formation experiments provided the basis for the generation of hydrogen gas hydrate kinetic. By different silicon - water quality than dry water-dispersible, silicon - water quality than 1:19 when dry water status and liquidity. Silicon - the water quality than 1:19 dry water reservoir of methane, the highest methane content within 12 h to 166.45 V / V, close to the ideal gas storage capacity 172.26 V / V. Then THF, TBAB, tBuNH2 synthesized as thermodynamic accelerator THF-H2, the TBAB-H2 and tBuNH2-H2 three dibasic hydrate, the hydrogen storage volume is not high. THF-H2 hydrate highest hydrogen storage capacity of 0.211 wt%, and only reach the ideal value of 20.2%; the TBAB-H2 hydrate highest hydrogen storage capacity was 0.097 wt%, as the ideal value of 24.5%; tBuNH2-H2 hydrate gas storage capacity 0.028 wt%, 1.8% of the ideal value. Pre accelerator was added to the dry water synthesized hydrogen gas hydrate, but the THF, the TBAB, tBuNH2 dry water structure has damaging effects, and therefore need to find a suitable promoting agent to ensure the stability of the dry water in the process of high-speed shearing. The final design of a visual jet reactor for efficient preparation of gas hydrates can kinetically accelerate the formation of the gas hydrate, and provides a new experimental apparatus and the experimental method for the synthesis of hydrogen gas hydrate.
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