Dissertation > Excellent graduate degree dissertation topics show

The Development of Type CTV-V Catalyst for Vinyl Acetate Synthesis by Ethylene Acetoxylation

Author: ZhouJian
Tutor: PanHeLin；XuHuiMing
School: East China University of Science and Technology
Course: Chemical Engineering
Keywords: acetoxylation vinyl acetate catalyst
CLC: TQ426.94
Type: Master's thesis
Year: 2012
Downloads: 51
Quote: 1
Read: Download Dissertation

Abstract


The catalyst for vinyl acetate by ethylene acetoxylation has been developed in this dissertation. With the present condition of industrial production, by the comparison and selection of the shape of the catalyst carrier, and properly increasing the amount of catalytic reactive component, at the same time keeping an appropriate Pd/Au atomic proportion, the type CTV-V catalyst for vinyl acetate in which reactive components are distributed like egg shell has been obtained on the base of type CTV-Ⅳcatalyst. As a result, the type CTV-V catalyst presents an obviously better catalytic performance. All the laboratory research and the pilot test gave a similar result, the preparation technique of the type CTV-V catalyst was steady and showed good repetition. The initial result from the 900ml catalyst testing unit indicated that performance of the type CTV-V catalyst has been greatly improved, in which the activeness has been increased by more than 46%, and the selectivity by more than 94%. The type CTV-V catalyst can meet the mighty demand for 150k ton/annual in SPC PVA plant. Besides the research developed a analysis testing approach of trace iodine which has great influence on catalyst. The experiment of acetic acid via carbonylation with various types of catalysts on different plants showed that iodine in unremoral deeply had great influence on the activeness and life-span of vinyl acetate Catalyst and the influence increases with the density of iodine.

Related Dissertations

  1. Study on Synthesis Intermediate of Vinyl Acetate Ethylidene Diacetate from DME and Syngas,TQ225.12
  2. Study on the Procees for the Preparation of Prohexadione and Its Analogs,TQ452
  3. Study on Using Sepiolite As Supported Catalysts in Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol,O643.32
  4. The Preparation of Polyaniline-Metal Complex and the Study on Its Catalytical Property,O634
  5. Synthesis and Characterization of Monovalent, Divalent Imidazolium Ionic Liquids Containing Hydrocarbons,O621.3
  6. Pt -based catalysts of direct methanol fuel cells,TM911.4
  7. The Study of Anode Catalyst Pd/C for Direct Formic Acid Fuel Cell,O643.36
  8. Study on the Synthesis of the Polypyrrole-Cobalt Oxides and Their Catalytic Behavior for the Electroreduction of H2O2,O643.32
  9. The Basicity of MO/ZrO2 Catalyst and Their Use in the Synthesis of 2-Ethyl-Hexyl Carbonate,O623.662
  10. Application of Charcoal Loaded Catalyst for Treatment of Organic Pollutants,X703
  11. Controllable Synthesis of Carbon Nanotubes Supported Metall Nanocatalysts and the Study on Their Electrocatalysis,O643.36
  12. Studies on Behavior of Potato Grafted Starch,TS103.846.1
  13. Xanthate Mediated Living Free Radical Polymerization of the Nonconjugated Vinyl Monomers,O631.5
  14. Preparation and Catalysis of Supported Palladium Nanoparticles Catalyst for Hydrogenation of 2-tertiary Butyl Anthraquinone to Produce H2O2,TQ123.6
  15. Research on Novel and Highly Efficient Modified Hybrid CrOx-B/SiO2 Catalyst for Ethylene Polymerization,TQ325.12
  16. Application of Hierarchically Macro-/Mesoporous Structured Metal Oxides to Hydrodesulfurization of Thiophene and Benzothiophene,TQ032
  17. Preparation of New Plate Structured Catalyst and Research of Their Catalytic Properties for DME Steam Reforming,TQ426.94
  18. Light Hydrocarbon Synthesis from Syngas on Fe-based Catalyst,TQ426.94
  19. Au/C Catalysts for the Heterogeneous-Fenton Degradation of Organic Contaminants,X703
  20. Properties of Zirconia Nanotube Arrays Loading Phospotungtic Acid,O614.412
  21. The Performance Study of ZrO2 Nanotubes Supported SO42-,O614.412

CLC: > Industrial Technology > Chemical Industry > Reagents and the production of pure chemicals > Catalyst ( catalyst ) > Chemical Industry Catalyst
© 2012 www.DissertationTopic.Net  Mobile