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Preparation of ZnO Nanostructure and Its Application on the Dye Sensitized Solar Cells
Author: CaiFangPing
Tutor: ZhuLiPing
School: Zhejiang University
Course: Materials Science and Engineering
Keywords: Zinc oxide Nanowire arrays Core-shell structure Dye-sensitized solar cells
CLC: TB383.1
Type: Master's thesis
Year: 2011
Downloads: 217
Quote: 0
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Abstract
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In this paper, we prepared by thermal evaporation of ZnO nanowire arrays vertically controlled by a simple spin-coating tetrabutyl titanate hydrolysis solution annealing TiO2 shell structure was successfully grown on ZnO nanowire arrays . Using scanning electron microscopy , high-resolution transmission electron microscopy , X -ray diffraction and photoluminescence spectra of various means of testing a detailed analysis of the morphology, structure and performance of the ZnO nanostructures . The following conclusions: (1) we get a the verticality good ZnO nanowire arrays by various pretreatment methods of research and analysis as well as the growth mechanism of substrate . ( 2 ) through the regulation of the seed layer film growth process parameters , we achieved a controllable growth of ZnO nanowire arrays . We find that the orientation and the grain size of the seed layer film directly affect the vertical orientation and the diameter of the nanowires , analysis of the various process parameters change nanowires entire column morphology . Explains the role of the seed layer in the growth process . (3) the first time we realized sintering the prepared ZnO/TiO2 of by a simple spin- coating a core-shell structure , the method is simple and convenient , replicable , and can be applied in the growth of other core-shell structure of the material . ( 4 ) Coating TiO2 nanowires array the solar dye sensitized battery performance comparison made ??of pure ZnO nanowire arrays , we have made a good photoelectric conversion efficiency of ~ 3% , an increase of 50% conversion efficiency , the main reason can be interpreted as coated TiO2 , due to a certain electron concentration difference between TiO2 and ZnO , thereby forming a self - built electric potential and optimized the photoelectric conversion efficiency of the battery , to a certain extent .
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