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Properties of small organic molecules photodiode based on ZnO nanowires
Author: MaWenMing
Tutor: YuJunSheng
School: University of Electronic Science and Technology
Course: Optical Engineering
Keywords: Chemical hydrothermal technology ZnO Nanowire arrays Organic - inorganic heterojunction Photodiode
CLC: TB383.1
Type: Master's thesis
Year: 2011
Downloads: 25
Quote: 0
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Abstract
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Preparation of semiconductor nanomaterials as well as their physical and chemical properties has aroused great concern, and the reason is because such materials generally have very significant quantum effect, surface effect, the size effect and special electronic conduction effect unique properties. Direct band gap semiconductor compounds as a wide band gap materials, zinc oxide (Zinc Oxide, ZnO) band gap of 3.37 eV at room temperature reaches up to 60 meV exciton binding energy, its chemical and physical properties of the fine . Among the research field of semiconductor nanomaterials, ZnO nanomaterials has become one of the largest research hotspot. The past 20 years, organic - inorganic heterojunction has a very attractive prospect in the field of electronics and optoelectronics, causing great concern for researchers in the scientific community. This particular structure, by using an inorganic material having a high carrier mobility and high absorption coefficients of the organic semiconductor material is combined, it will greatly improve the performance of the device. The special structure of the device, on the other hand, can usually be performed by a low-cost solution method to be prepared, which makes the structure have the huge advantage in the cost. The paper in order to make further in-depth study of the hot issues based on ZnO research areas, the use of chemical method, successfully prepared ZnO nanoparticles and ZnO nanowires (Nanowires, NWs) array, and on this basis, based on ZnO nano - Preparation of small organic molecules mixed photodiode (Photodiode) and photoelectric properties. Specific research contents are as follows: (1) the use of chemical hydrothermal technology to prepare high-quality ZnO nanoparticles (Nanoparticles, NPs), and its structure by SEM (Scanning electron microscope, SEM), XRD (X-ray diffraction, XRD) and morphology characterized by UV - visible absorption spectrum (Ultraviolet-visible absorption spectrum, UV-Vis) and photoluminescence spectra (Photoluminescence, PL) test showed that ZnO nanoparticles with good optical properties. (2) the use of chemical hydrothermal and annealing processes were successfully prepared ZnO Nanowire Array on ITO substrate. And does not use any form of the catalyst, in the experiment in order to avoid introducing a new impurity defects. For the preparation of samples, we tested its characterization means of SEM, XRD, PL and UV-Vis, we found from the test results of ZnO nanowire arrays with a very good crystalline quality and morphology Meanwhile, we also found that the ZnO nanowire arrays room temperature emission bands, each with a green and ultraviolet region has unusually excellent optical characteristics. ZnO nanowire arrays grown by chemical hydrothermal technology, and take advantage of the vacuum evaporation technique, small organic molecules deposited on ITO as a substrate of ZnO nanowire arrays using Ag as the anode (3), assemble the most basic organic - inorganic heterojunction structure of ZnO nanowire photodiode. IV characteristics of test instruments produced of ZnO nanowires photodiode IV characteristics test analysis, the results showed that the photodiode good rectifying characteristics to achieve the basic requirements of the photodiode applications.
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