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This thesis is divided into four parts : First review of the development of gas chromatography and capillary gas chromatography , a brief introduction to the method of evaluation of column performance , roughening of the inner wall of the capillary column , go live coated characteristics , summed up the cup aromatics and their derivatives in gas chromatography and gas chromatography in recent years in environmental chemistry . 2. This thesis roughening treatment with sodium chloride and deposition method , fused silica capillary column and static method using high temperature a roughened capillary column coated variety of different polarity of the stationary phase , which is given in It should be noted that the problem of capillary roughening process . The article also studied three kinds of new calixarene phosphate derivatives stationary phase : ( 1 ) 5,11,17,23,29,35 - Uncle Six butyl -25,26,27,28,29,30 - six oxygen phosphoric acid dimethyl ester calix [ 6] arene ; ( 2 ) 5,11,17,23,29,35,41,47 - Uncle Eight butyl -25,26,27,28,29,30,31 32 - eight oxygen phosphoric acid dimethyl ester calix [8 ] arene ; ( 3 ) 5,11,17,23,29,35,41,47 - Uncle Eight butyl -25,26,27,28,29,30 , 31, 32 - eight oxygen dipropyl phosphate Cup [ 8 ] arene , examines the performance of the three kinds of stationary phase in gas chromatography under different proportions . These stationary phase has good film formability, high column efficiency, having a good separation effect similar substances on and aromatic homologues and position isomers . The introduction of the phosphate ester functional groups changed calixarene cavity structure ; calixarene substituted on the size of the group , polarity, the shape of the object molecules of the π-π interactions play a key role for the identification of the guest molecule . We use homemade the novel capillary column ( mixed stationary phase ) of benzene and other pollutants in the adhesive preliminary test results show that its easy operation , fast analysis , high sensitivity.
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