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Study on the Preparing of KGM-PVA/CA Adhesive
Author: ZhangJia
Tutor: GuoKangQuan
School: Northwest University of Science and Technology
Course: Agricultural Products Processing and Storage
Keywords: CA KGM PVA Adhesives
CLC: TQ437
Type: Master's thesis
Year: 2010
Downloads: 11
Quote: 0
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Abstract
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In order to solve the problem of free formal dehyde in the wood adhesives, a new,green and renewable wood adhesive had developed. The free formal dehyde would pollut the environment and endange human health.The new wood adhesive is composed of KGM, CA, PVA, glacial acetic acid and water. The adhesive bonding performances of the mixture were studied. Including the following four aspects:Part I:Preparation of chitosan adhesive acidification process. Part II:konjac glucomannan/chitosan blend adhesive preparation process. Part III:KGM-PVA/CA blend adhesive preparation process. Part IV:Exploring the KGM-PVA/CA adhesive reasonable parameters for the plate. The main conclusions of this paper are as follows:(1) By studying the chitosan acidic optimum conditions, has been modified. Adhesive system in 1% acetic acid, gel reaction time was 24h of aging condition, the adhesive bonding performance is the best.(2) By studying the KGM/CA blend adhesive preparation process, can be seen:the amount of chitosan, the amount of konjac glucomannan, konjac glucomannan and chitosan in the interaction of adhesive would affect bonding strength. The dry bonding strength is 3.21MPa, and wet-like bonding strength is 1.6MPa.(3) Joining PVA as a modifier in the KGM/CA blend adhesive prepared ternary blend adhesive. By orthogonal test:the dry bonding strength is not changed obviously:the wet bonding strength is significantly increased. The dry adhesive bonding strength of ternary blend is 3.5MPa, wet-like bonding strength is 2.35MPa.(4) Through the orthogonal plywood hot press molding, obtained the best hot pressing parameters:pressing temperature 130℃, hot pressure 4MPa, pressing time 15min, placed plastic aging time 24h. According to the test parameters were verified, the bonding strength of plywood reached the top. The dry bonding strength is 4.01MPa, wet-like bonding strength is 2.88 MPa.Conclusions of this study will accelerate the process and development of wood adhesives. Those conclusions will provide assistance and scientific evidence in establishing and improving the adhesive processing conditions. Three kinds of polymer blends with very good water resistance of modified adhesive properties, will have good development in agro-processing.
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CLC: > Industrial Technology > Chemical Industry > Adhesive Industry > All purpose adhesive
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