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Study on the Bioactive Components from a Traditional Mongolian Medical Herb Clematis Aethusaefolia Turcz.
Author: FuMingHai
Tutor: BaoBaoQuan
School: Inner Mongolia University for Nationalities
Course: Monte Pharmacy
Keywords: Celery leaves clematis Biological activity Flavone C-glycosides
CLC: R29
Type: Master's thesis
Year: 2011
Downloads: 62
Quote: 0
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Abstract
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Objective: The topics to Mongolia herbs parsley leaves clematis Clematis aethusaefolia dried aerial parts of Turcz study , extraction and separation select a valid active site of purified monomer compounds for the structural identification , and hope that the discovery of new compounds and bioactive a monomer compound. Method : take Turcz , Clematis aethusaefolia , clematis , celery leaves dried aerial parts of 10.6kg appropriate crushed , extracted with 75 % ethanol three times , concentrated alcohol solution to get bold material extract 1.53kg . The bold was extract add water suspension , washed with equal volumes of petroleum ether , chloroform , ethyl acetate , n-butanol and extracted three times the recovery solvent under reduced pressure . Obtained the different polarity extract, shrimp eggs lethal experimental determination of the biological activity of each of the extracted layer , select the effective parts , using a reverse phase silica gel column chromatography , thin layer chromatography , Sephadex LH -20 , semi-preparative HPLC method further separation and purification, to obtain a monomer compound . Check the purity of the melting point, high-performance liquid chromatography method , and the use of modern methods of 1H-NMR, 13C-NMR, HMBC, MS structural identification of compounds were obtained , and its discovery of new compounds and biological activity of single donor compound. Results: 11 compounds were obtained by separation of the ethyl acetate layer of the chemical composition of the extract of the the celery leaves clematis Clematis aethusaefolia Turcz effective active site , and its structure identification . The quercetin of determining the chemical structure of ferulic acid caffeic acid (1) (2) apigenin ( 3) luteolin biotin- 3'- 0- glucoside (4) -3-0 - glucoside ( 5) aliena the mesothelin the -3-0 - rhamnosyl (1-6 ) glucoside (6), kaempferol -3-0 - rhamnose - (1-6) - apigenin glucoside ( 7 ) -7-0 - ( P - coumaroyl ) apigenin glucoside ( 8 ) -6 - C -6 \butyl ester ( 11) . conclusions: The effective active site of celery leaves clematis clematis aethusaefolia Turcz ethyl acetate layer chemical composition , total of 11 compounds were isolated , and the use of 1H- NMR , 13C - NMR , HMBC, MS to determine the structure of the compound and the 11 compounds were first isolated from the plant . apigenin - 6 - C -6 \
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