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Manganese oxide particles in water and ZnO on TiO_2 photocatalytic bactericidal activity

Author: ZhuZuo
Tutor: LiuJingZe;MaZiChuan
School: Hebei Normal
Course: Ecology
Keywords: Photocatalytic Sterilize TiO2 ZnO Manganese oxide E. coli
CLC: Q93-3
Type: Master's thesis
Year: 2010
Downloads: 88
Quote: 1
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Abstract


Photocatalytic disinfection technology because of low consumption, high efficiency and other characteristics of much attention, in water treatment has also been more widely used. Water treatment to kill pathogens in drinking water treatment in particular extremely important part. Water to be treated not only contains a variety of pathogens, there are many particulate impurities which affect the photocatalyst particles by the nature or the photocatalytic process, can affect its photocatalytic activity. This paper selected two commonly used photocatalyst TiO 2 and ZnO as a drinking water purification instructions to kill bacteria Escherichia coli ATCC 8099, select contaminated water three common manganese oxide particles α- MnO 2 , β-MnO 2 and γ-MnOOH as an impurity particles. The main contents of the study are: ultraviolet excitation light sources of different TiO 2 bactericidal activity, different crystal manganese oxide particles on TiO 2 and ZnO photocatalytic bactericidal activity, different initial pH values ??(4.0,6.0,8.0) manganese oxide particles on TiO 2 and ZnO photocatalytic bactericidal activity of different concentrations of manganese oxide particles on TiO 2 and ZnO photocatalytic bactericidal activity, different excitation light sources of manganese oxide particles on TiO 2 and ZnO photocatalytic bactericidal activity. Found that with shorter wavelength excitation light source and light intensity enhancement, TiO 2 bactericidal activity was enhanced; manganese oxide particles on TiO 2 strong photocatalytic bactericidal activity inhibition, and the α-MnO 2 strongest inhibition, γ-MnOOH followed, β-MnO 2 Again, while manganese oxide particles photocatalytic bactericidal activity of ZnO almost no inhibition; bacterial suspension initial pH on manganese oxide particles on TiO 2 inhibition of photocatalytic bactericidal activity have a greater impact, initial pH 8.0, the strongest inhibition, pH, is 4.0 second, pH value 6.0 again, and for ZnO, and manganese oxide particles of the three pH values ??are not inhibit the photocatalytic bactericidal activity; with the bacterial suspension concentration increased manganese oxide, TiO 2 photocatalytic bactericidal activity is inhibited also increases, while the ZnO photocatalytic activity even with higher concentrations of manganese oxide is not co-suppressed, increasing the concentration of manganese oxide can not be to impact; long wavelength excitation light irradiation, TiO 2 photocatalytic activity may be the inhibition of manganese oxide particles, short-wave excitation light irradiation, the manganese oxide particles produce inhibition of its greatly reduced, regardless of the longwave or shortwave excitation source, manganese oxide ZnO particles were unable to suppress the photocatalytic bactericidal activity. In summary, ZnO as a photocatalyst, the bodies of water of manganese oxide particles having stability, TiO 2 photocatalyst in the long-wavelength excitation light source, the bactericidal activity of the photocatalytic particles may be manganese oxide inhibition by short-wave excitation light irradiation greatly reduced inhibition.

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