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Fe_3O_4 magnetic nanoparticles - graphene oxide composites Controllable Preparation and Application
Author: Zhang
Tutor: YangZuPei;ZhangZhiJun
School: Shaanxi Normal University
Course: Materials Science
Keywords: Fe3O4 magnetic nanoparticles Graphene oxide Composites Controllable Preparation Characterization Application
CLC: TB383.1
Type: Master's thesis
Year: 2011
Downloads: 812
Quote: 0
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Abstract
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Magnetic nanoparticles unique magnetic properties make it widely in many fields of application. Magnetic nanoparticles is a prerequisite for application of the monodisperse particle size and controllable, and has better magnetic response. Carbon material graphene, with its excellent features, in recent years has been rapid development. Magnetic nanoparticles - graphene oxide nanocomposites as a novel nanocomposites, set magnetic nanoparticles and graphene oxide features in one, is expected to be functional materials, chemical and biological fields is widely available. The master's thesis studied the Fe3O4 magnetic nanoparticles - graphene oxide composites are discussed Fe3O4 magnetic nanoparticles graphene oxide surface controlled assembly and preliminary study of the composite material in the removal of tetracycline and other aspects of environmental pollutants Application. Prepared using pyrolysis diameter were 3 nm, 5 nm, 6 nm, 18 nm Fe3O4 magnetic nanoparticles soluble and ligand-exchange chromatography with surface carboxyl and amino modification. The particle size of the magnetic nanoparticles, structure, magnetic properties and the surface electric charge were characterized. The results show that we successfully prepared a higher magnetic response, good monodisperse Fe3O4 magnetic nanoparticles. Surface chemical modification of the magnetic nanoparticles have good aqueous stability. Thesis Chapter 3, by changing the Fe3O4 magnetic nanoparticles Fe304 magnetic nanoparticles - graphene oxide composites loadings, to control the magnetic properties of the composite. The use of polyethylene imine (PEI) chemical crosslinking graphene oxide, to obtain amino graphene oxide (GO-PEI), with different amounts of Fe3O4 magnetic nanoparticles crosslinking reaction to obtain a different load ratio of magnetic nanoparticles - graphene oxide composite material (M-GO). Through the composite morphology, structure, and magnetic characterization, that the composite material has magnetic properties can be regulated. Chapter 4 Research papers by assembling technology, Fe3O4 magnetic nanoparticles - graphene oxide composite Fe3O4 magnetic nanoparticles on the surface of the graphene controlled assembly. The use of polyethylene imine (PEI) may be at higher temperatures the characteristics of graphene oxide reduction, and the amino group carried PEI graphene oxide carried by reaction of the carboxylic acid groups, PEI modified graphene oxide reduction (PEI -rGO). And PEI-rGO with DMSA modified Fe3O4 magnetic nanoparticles in the presence of EDC chemical reaction to achieve the Fe3O4 magnetic nanoparticles assembled orientation graphene oxide, to obtain a composite magnetic graphene oxide (M-rGO). With this magnetic composite material contains a large conjugated system characteristics, a preliminary study of the composite material in the removal of tetracycline and other environmental pollutants and other applications. Research development functionalized graphene oxide magnetic composites method is simple, controllable advantages of the composite material has high superparamagnetic. Magnetic resistance class features expected in graphene composite magnetic targeting drug / gene transport, magnetic resonance angiography, and magnetic-mediated biological separation and removal of environmental pollutants and fields of application.
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