Dissertation > Excellent graduate degree dissertation topics show

Synthesis of Dithioamino Starch Xanthogenate and Its Applicationin Absorption of Heavy Metal lons in a Aqueous Solutions

Author: LuDongLiang
Tutor: XiaZuo
School: Guangxi University for Nationalities
Course: Applied Chemistry
Keywords: Starch Heavy metal ions Xanthate Adsorption
CLC: X703
Type: Master's thesis
Year: 2010
Downloads: 145
Quote: 0
Read: Download Dissertation

Abstract


And yellow reaction between the soluble starch and acrylamide graft copolymer as the theoretical basis , a creative synthesis of the dithiocarbamate starch xanthate ( DSX ) and used for the adsorption of heavy metal ions from wastewater , main content and conclusions are as follows : instruments such as FTIR, H-NMR, (13) C -NMR, XRD, SEM and TG thiocarbamate synthesized starch xanthates DSX characterization results showed that the the thiocarbamate starch xanthan salt ( DSX ) was successfully prepared . Investigated the synthesis of cross-linking agent , triggering agent , acrylamide , and the amount of carbon disulfide and other factors , the synthetic products used in the treatment of heavy metal ions , the use of orthogonal experiment looking for heavy metal ion removal rate is relatively high DSX synthesis conditions , the results : crosslinking agent material than 10g ︰ 1.25 mL , the optimum conditions of the initiator material than is 10g ︰ 4ml acrylamide materials for ︰ 3ml 10g and carbon disulfide materials than is 10g ︰ 5ml . In addition, soluble starch and acrylonitrile graft copolymerization synthetic dithiocarbamate starch xanthates ( DSX - 1 ) and is copolymerizable with the acrylic acid graft the synthetic disulfide ester groups starch ( DTS ) . The effects of temperature, pH , ion concentration and dosage amount and other factors DSX applied to deal with the impact of the heavy metal ions from wastewater , uniform design experiments to find the optimum conditions of the treatment of heavy metal ions , experiments show that : a temperature of 40 ° C , pH value of 9 , the adsorption time is 50min, the ion concentration to 15 mg / L , the dosage to 0.2 g , the the Cu 2 < / sup > the the Pb 2 < / sup > CD 2 < / sup> and the Zn 2 < / sup > four kinds of metal ions highest removal rate were 98.5% , 98.3% , 97.8% and 97.5% , respectively . Langmuir and Freundlich isotherm equation and pseudo - first - order kinetics and second-order kinetics DSX adsorption the Cu 2 < / sup > the Pb 2 , Cd the 2 and Zn 2 of heavy metal ions adsorption process is described , the results show that : this adsorption is more in line with the Langmuir adsorption isotherm and a kinetic equation .

Related Dissertations

  1. Density Functional Theory Study of Dimethyl Ether Adsorption on the Low-Index Pt Surface,O485
  2. Preparation and Properties of Highly Active Dietary Fiber and Carboxymethylcellulose from Gracilaria Residue,TS254.9
  3. Establishment of ELISA for Detecting Cd-MT of Pteria Penguin and Preliminary Study of ELISA-kit,X835
  4. Numerical Study on Phosphorus Distribution in Water Environment of the Three Gorges Reservoir,X832
  5. Under microaerobic conditions closed calcium carbide furnace exhaust COS gas adsorption purification,X781
  6. Study on the Preparation of Medical Grade Glycerol from the By-product of Jatropha Biodiesel,TQ223.163
  7. Experiment Study of the Biogas Purification Process by Zeolite Filling Washing,TQ221.11
  8. Studies on the Properties of Starch from Germinated Polished-rice-with-germ,TS235.1
  9. Preparation of Activated Carbon from Tobacco Stems and Application for Low Concentration Phosphine Adsorption,X712
  10. Concentrations of Lipids in Grains of Japonica Rice: In Response to Nitrogen Fertilizer and in Relation to Physicochemical Properties of Rice Flour,S511.22
  11. Research on the Physiology Mechanism of Grain Filling of inferior Grain during Day and Night Chemical Regulations,S511
  12. Syntheses, Structures and Properties of Metal-organic Frameworks Based on Dicarboxylate Ligands,O621.13
  13. Effect of Flaxseed Gum on Pasting and Retrogradation of Corn Starch and Application on Flaxseed Gum on Emulsion-Type Sausage,TS231
  14. Adsortions of Dye by Modified Activated Carbon and Heavy Metals by Rice Husk-Based Activated Carbon,X703
  15. Research on the Plasticizers of Starch Sizing Agents,TS103.846.1
  16. Treatment of Effluent Water from Bio-flocculation Adsorption Technology by Biological Aerated Filter (BAF),X703
  17. Research on Detection of the Carbamate Pesticides by Aminoacids-matal Ions Films Chemically Modified Sencor,S481.8
  18. Study of the Structure of Wall-Inspecting Robot on Chemical Container in Service,TP242
  19. Influence of Aromatic and Nitrogen Compounds on Desulfurization onto Activated Carbon,TE624.5
  20. Study on Removal Characteristics of Dissolved Organic Matters from Bio-treated Effluent of Dye Wastewater by Activited Carbon Adsorption,X791
  21. Characteristics of synthesis of poly- p-phenylenediamine and its adsorption of sulfate ions,X703

CLC: > Environmental science, safety science > Processing and comprehensive utilization of waste > General issues > Wastewater treatment and utilization
© 2012 www.DissertationTopic.Net  Mobile