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Study on Formation Mechanism of Blast Furnace Hearth Sediment of High Alumina and Titanium
Author: ChenHongJian
Tutor: LvQing
School: Hebei University of Technology
Course: Iron and steel metallurgy
Keywords: Blast furnace Vanadium-titanium magnetite Hearth sediments Ti ( N , C )
CLC: TF549
Type: Master's thesis
Year: 2008
Downloads: 37
Quote: 0
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Abstract
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Chengde Steel blast furnace smelting of vanadium-titanium magnetite found in the overhaul of the blast furnace blast furnace bottom and hearth in the presence of large amounts of sediment , sediment bottom of the pot - shaped distribution in the hearth , a serious impact on blast furnace anterograde . This article studies the causes and mechanism of the Order of the steel, aluminum, titanium sediment . Sediment composition and properties of bearing steel blast furnace hearth , the results show that the order of the BF sediment was black , wrapped with a metallic luster iron , high hardness, and the molybdenum disilicide furnace in 1600 when softened but does not melt . High-melting substances in sediments spinel and TiC , TiN and their solid solution of Ti ( N , C ) and Ti ( C , N ) . TiC is mainly distributed in the circumference of the metallic iron , the main aggregates of Ti ( C , N ) and Ti ( N , C ) and the compound dispersed in the spinel or aluminum di - calcium and rutile . The sediment can be divided into molten iron layer the titanium deposition layer and transition erosion layer . Molten iron layer containing metallic iron ; the lower portion of the molten iron layer deposited layer is titanium , titanium carbide and titanium nitride, and solid solutions thereof , and magnesium aluminate spinel ; transition erosion layer erosion of the refractory material to molten iron and slag from the upper to the next , aluminum and silicon content increases gradually, iron, titanium content decreased . Hearth deposit formation mechanism: titanium slag and coke generated TiC a direct reduction reaction , with the formation of the liquid iron and slag TiC iron drops adsorption , wrapped around the iron drops . TiC wrapped in liquid iron from sinking to the bottom of the furnace to form a hearth sediments ; slag - iron interface and hot metal - hearth refractories interface due to the existence of concentration and temperature gradients precipitation of Ti ( N , C ) . Ti ( N , C ) , the reunion of molten iron and slag formed in the hearth hearth sediments . Order of BF deposit formation is mainly due to the presence of large amounts of carbon and aluminum slag viscosity increases , reducing the fluidity of the slag , the slag in the slag in the high-melting substance enriched sediment formed . Obtained by experiment to ensure blast furnace anterograde Chengde Steel blast furnace slag basicity should be controlled at about 1.02 and not more than 1.22 . Slag MgO content between 11.95% to 13.95% . Use of the pyrolusite washing furnace can reduce the melting point of the sediment , eliminate sediment .
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CLC: > Industrial Technology > Metallurgical Industry > Ironmaking > Blast furnace operation > Blast furnace failure and to prevent
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