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The Synthesis and Application of Poly Epichlorohydrin

Author: ZhaoXiaoXing
Tutor: WuGuangFeng
School: Changchun University of
Course: Polymer Chemistry and Physics
Keywords: Polyepichlorohydrin (PECH) Chlorinated polyvinyl chloride (CPVC) Plasticizer Glass transition temperature
CLC: TQ325.3
Type: Master's thesis
Year: 2011
Downloads: 25
Quote: 0
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This experiment polyepichlorohydrin (PECH), the synthesis of five different molecular weight as a novel plasticizer , experiments using different mass fraction of mechanical blends prepared CPVC / PECH mixture to reduce its glass transition temperature, and using dynamic mechanical analyzer (DMA), thermal gravimetric analyzer PECH MW tensile test , there is shown a differential scanning calorimeter , the glass transition temperature ; CPVC / PECH blend has a glass transition temperature, thermal stability . The results show that when the PECH in an amount not exceeding 20% wt , the glass transition temperature of the CPVC / PECH blends reached the lowest is 20 ° C lower than a glass transition temperature of the pure CPVC . Study found five molecular weight of the PECH , the plasticizing effect of the molecular weight of 2840 is ideal, and in Blends With PECH content increases , when the high or low molecular weight of the plasticizer PECH plasticized effect not obvious PECH of a molecular weight of between 2000 to 3000 , has the best plasticizing effect . By the mass fraction of the different proportions of the PECH be blended with CPVC , found that 20% of the ratio of PECH ideal . Add dibutyltin laurate can significantly improve the thermal stability of the CPVC / PECH blend in the blend .

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CLC: > Industrial Technology > Chemical Industry > Synthetic resins and plastics industry > Polymer resin and plastic > PVC and plastic
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