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Study on Styrene-Butyl Acrylate Emulsion Adhesive
Author: PengMin
Tutor: YuShaiCheng
School: East China University of Science and Technology
Course: Chemical processes
Keywords: Acrylate emulsion adhesive Emulsion Polymerization Styrene-acrylic emulsion Water absorption Midsole insole
CLC: TQ433.434
Type: Master's thesis
Year: 2011
Downloads: 188
Quote: 0
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Abstract
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Acrylate emulsion polymer adhesive is one of the important applications of the emulsion polymerization techniques . Acrylic emulsion adhesive status quo introducing footwear non-woven adhesives were a large number of experiments and research work focuses on the emulsion adhesives , styrene-acrylic emulsion polymerization process and bottom insole coated sizing preparation process the various factors that affect the performance of the final product , the use of chemical engineering principles to the analysis of the deficiencies in the existing technology and improved methods , and provide technical guidance to solve production problems , and further scientific research to provide a reference for emulsion polymerization ideas. Characterization methods to characterize the structure of the styrene-acrylic emulsion polymers , combined with the concentration of styrene-acrylic emulsion product rate , solid content , conversion rate, film water absorption properties of the test , as well as the final product in the bottom insole FTIR.DSC analysis hardness and water absorption test , the original factory recipe monomer , emulsifier , initiator agent and process reaction conditions improve , and ultimately achieve improved performance of styrene-acrylic emulsion adhesive and shoes in the bottom pad . The major findings include : (1) for the experimental program to determine the final set of best optimization formulations and excellent operating process . Using pre- emulsification method, the semi-continuous polymerization process in conjunction with the seed emulsion wears ; monomer ratio St / MMA / BA / MA = 45/15/10/42 ; functional monomer in an amount of acrylic acid (AA) and N- the amount of methylol acrylamide (NMA) are used in an amount of 3% of the total monomer ; emulsifying system of the anionic emulsifier (DB-45) and non-ionic emulsifying agent ( OP - 10 ) of the complex , and the proportion of complex m (DB-45) / m (OP-10) = 3/1. (2) the use of the laboratory test conclusion to the factory amplification test , and the research improved emulsion styrene-acrylic emulsion original factory for factory non-woven fabric coated sizing , eventually finished bottom insole ; comparative samples at the same time also to enlarge the application of experimental samples and the original factory performance testing, the results show that : the midsole insole sample of this research project the main performance indicators are better than the comparative samples provided by the factory .
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CLC: > Industrial Technology > Chemical Industry > Adhesive Industry > Synthetic adhesive > Rubber, resin as raw material adhesive > Synthetic resin adhesive of the raw materials > Polyolefin adhesives
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