Dissertation > Excellent graduate degree dissertation topics show

Synthesis and Structures of Transition Metal Complexes with Schiff Bases

Author: ZhouPeng
Tutor: HuiRuiHua;YouZhongLu
School: Liaoning Normal University
Course: Inorganic Chemistry
Keywords: Schiff base complex synthesis crystal structure supramolecular self-assembly
CLC: O641.4
Type: Master's thesis
Year: 2008
Downloads: 98
Quote: 0
Read: Download Dissertation

Abstract


Schiff base complexes are formed through the condensation of aldehydes or ketones with primary amines. The Schiff base compounds usually contain O, N and any other donor atoms, which easily form versatile complexes with metal ions. In recent years, much interest has been focused on the Schiff base compounds and their complexes. The Schiff base complexes have been widely used in the magnetic materials, catalysis, biological activity and many other fields.Study on the interactions between metal ions and the Schiff base ligands is important for the investigation of their properties and applications. In order to further investigate the synthesis and self-assembly of the Schiff base complexes, 17 Schiff base ligands derived from salicylaldehyde had been designed and synthesized. 24 Schiff base complexes had been synthesized and their crystal structures have been determined by X-ray diffraction. The influence of the reaction conditions, proportion of starting materials, solvents, anions, bridging groups, etc. on the structures of the complexes have been investigated.As a result, the reaction conditions, the proportion of starting materials, solvents, anions, and bridging groups, have important influence for the structures of such complexes.

Related Dissertations

  1. Studies on the Synthesis and Technology of Dipentaerythritol and Its Derivative,TQ223.164
  2. Synthesis and Characterization on Semi-Aromatic Polyamides Containing Benzoxazole Units,O633.5
  3. Hydrothermal Synthesis of Oxide Hollow Spheres,TB383.4
  4. Video Coding Research Based on Texture Characteristics,TP391.41
  5. Research on the Workflow Technique for the Complex Simulation Systems VV&A,TP391.9
  6. Humanoid Robot Soccer System Based on Global Vision System,TP242.6
  7. Poetic alienation : graphics,J506
  8. Urothermal Synthesis, Structure and Characterization of Functional Coordination Polymers,O631.3
  9. The Total Synthesis of a Flavonoid Glycoside Apigenin-7-O-β-D-glucuronide,R284.1
  10. The Regulate and Controlof Slug on P53-MDM2 System,R730.2
  11. Study on the Syntheses and Antibacterial Acticity of Metal Organic Complexes Built from Three Carboxylate Ligands,O621.13
  12. Atovaquone analogues Design, Synthesis and antitumor activity of,R914
  13. Research on New Method for Measuring Dielectric Constant of Microwave Samples,O441.6
  14. Synthesis and Seperation of 1,1’-binaphthol,O625.3
  15. Gao Zhong-ying academic thought and experience and use of Bufei Decoction treatment of common diseases of the respiratory system drug law,R249.2
  16. Flexible,rigid,Synthesis and characterization of mixed ligand complexes,O621.1
  17. Characterization and Properties of capsaicin / CD system,TQ450.1
  18. Synthesis and Performance Study of Bisphenol AP-based Polybenzoxazines,TQ320.1
  19. Study on Spinning of High Viscosity Polyamide-6/Rare Earth,TQ340.64
  20. Study on the Synthetic Process of Vat Pink R,TQ616.2
  21. Study on the Mechanism of Night Temperature to Grain Filling of Inferior in Rice,S511

CLC: > Mathematical sciences and chemical > Chemistry > Physical Chemistry ( theoretical chemistry ),chemical physics > Structural Chemistry > Complex chemistry ( coordination chemistry )
© 2012 www.DissertationTopic.Net  Mobile