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Natural dye -sensitized solar cell
Author: LuoPeiHui
Tutor: NiuHaiJun
School: Heilongjiang University
Course: Polymer Chemistry and Physics
Keywords: Natural dyes Dye-sensitized solar cells Titanium dioxide Electrophoresis High voltage electric field
CLC: TM914.4
Type: Master's thesis
Year: 2010
Downloads: 257
Quote: 0
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Abstract
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By modified sol - gel method and hydrothermal method Synthesis of titanium dioxide particles of two different sizes of these two types of titanium dioxide particles with a commercial P25 two titanium oxide mixed to prepare titanium oxide particles of a submicron size , known as the three $ coated spherical titanium dioxide (Ternary-encapsulated spherical TiO2, TES-TiO2). Preparation TES -TiO2 is deposited by cathodic electrophoretic deposition technique on Nanocrystalline mesoporous titania (Mesoporous TiO2, Meso-TiO2) coated with a fluorine-doped tin oxide conductive glass (Fluorine-doped SnO2 glass, FTO) was prepared for Dye sensitized solar cell bilayer titania electrode . Compared with double Meso-TiO2/P25 electrode , based Meso-TiO2/TES-TiO2 electrode in dye-sensitized solar cell energy conversion efficiency of 6.49% 9.3% 5.94% than Meso-TiO2/P25 electrode . The secondary crystallization prepared the double Meso-TiO2/TES-TiO2 electrode high temperature calcination , while the introduction of a high voltage electric field (High-voltage electric field, HVEF) . As a result, the efficiency of dye-sensitized solar cell is changed from 6.49% to 7.05% further increase of 8.6% . Obviously, compared with the usually applied to the dye- sensitized solar cell active layer , about 20 nanometers of titanium dioxide particles , preparation having a sub- micron size , porous TES-Ti02 not only increases the light scattering effect, while promoting the dye molecules adsorption and diffusion of the electrolyte . Furthermore , HVEF the introduction to provide the connection between the better of titanium dioxide particles , so that the electrons in the titanium dioxide more easily transferred, to avoid the recombination of the charge . First reported in this paper canna, red string and Solanum nigrum extract as dye-sensitized solar cell photosensitizers . Canna red string , Persimmon and assembled into Solanum nigrum as a sensitizer dye-sensitized solar cell energy conversion efficiency of 0.29% , 0.26% , 0.13% and 0.31% , respectively . By Fourier transform infrared spectroscopy and UV - visible absorption spectroscopy to study the molecular structure of the four natural dyes and optical absorption , electrochemical impedance spectroscopy impedance of the battery internal interface . The results show that there is a higher impedance to persimmon photosensitizer in the dye - sensitized solar cell , at the interface .
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CLC: > Industrial Technology > Electrotechnical > Independent power supply technology (direct power) > Photocell > Solar cells
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