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In this thesis, allyl ether series compounds - trimethylolpropane diallyl ether and quarter tetraol triallyl ether synthesis, and experimental determination of allyl alcohol - methanol, allyl alcohol - ethanol and allyl alcohol - water vapor-liquid equilibrium data. First, trimethylol propane, sodium hydroxide and allyl chloride as raw materials, in the role of a phase transfer catalyst, synthesized by the Williamson ether reaction of trimethylolpropane diallyl ether. The mass fraction of the aqueous NaOH, the catalyst with the ratio of the mass of trimethylolpropane, and the reaction temperature and catalyst type on the reaction yield. Three factors and three levels of response surface methodology to optimize the process conditions, trimethylolpropane diallyl ether synthesis of optimal process conditions. The results show that: the selection of tetrabutyl ammonium bromide as a catalyst, the reaction temperature is 75.2 ° C, the mass fraction of the NaOH solution was 38.5%, the ratio of the mass of the catalyst, and trimethylol propane was 14.5% obtained when the tris (hydroxymethyl) propane diallyl ether, 91.2% of the highest yield. Secondly pentaerythritol, sodium hydroxide and allyl chloride as raw materials, in the role of a phase transfer catalyst, by the Williamson ether reaction of the synthesis of pentaerythritol triallyl ether. Response surface methodology to investigate the impact on the yield of the product of the reaction temperature, and the mass ratio of the mass fraction of NaOH solution and catalyst and pentaerythritol, and the prediction model. The results show that: the ratio of the mass of the mass fraction of aqueous NaOH solution and the catalyst and pentaerythritol these two factors is significant, impact on the yield of the reaction temperature and the ratio of the mass of the catalyst with pentaerythritol interaction significantly affected. Pentaerythritol triallyl ether synthesis of optimal process conditions are obtained: tetrabutyl ammonium bromide as a catalyst, the reaction temperature was 78.0 ° C, the mass fraction of the NaOH solution was 54.9%, the ratio of the mass of the catalyst and pentaerythritol was 11.1% the highest yield of 70.2%. Finally, the experimental determination of allyl alcohol - methanol, allyl alcohol - ethanol and allyl alcohol - water binary system than 101.33kPa under the vapor-liquid equilibrium data and experimental data Herrington on the thermodynamic consistency test results show that the three The the group binary system phase equilibrium data are in line with the thermodynamic consistency. Respectively associated with NRTL and Wilson activity coefficient model NRTL and Wilson model parameters for three binary systems at atmospheric pressure at the same time with the optimization of the method of least squares projections to get the vapor-liquid equilibrium. By allyl alcohol - methanol system, the Wilson equation, vapor phase maximum deviation of 0.0095, the average deviation of 0.0318, g12-g11 value -3572.51, g21-g22 value -3543.27; NRTL equation, the vapor phase, the maximum deviation 0.0094, the average deviation of 0.0459, g12-g11 value -4423.03, g21-g22 value -4591.73 α12 value of 0.3. Two equations is quite fitting accuracy of the system the Wilson model associated results. Allyl alcohol - ethanol system, Wilson equation, the vapor maximum deviation of 1.7037, the average deviation of 0.2129 g12-g11 value -4790.92, g21-g22 value -2762.64; NRTL equation vapor maximum deviation of 1.0561 The average deviation of 0.0587, g12-g11 value -3474.24 g21-g22 value -7761.92. Two equations, quite fitting accuracy of the system, the NRTL model associated results. Allyl alcohol - water system, Wilson equation, vapor maximum deviation of 0.0516, the average deviation of 0.1617, g12-g11 value of 12250.5, g21-g22 value -2140.81; NRTL equation vapor maximum deviation of 0.0582 The average deviation of 0.1585, g12-g11 value -7344.16 g21-g22 value -4987.03. Two equations, quite fitting accuracy of the system, the NRTL model associated results. VLE data trimethylolpropane diallyl ether of industrial production design provides reference data.
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