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Syntheses and Properties of Calix "4" Arene Derivatives with Ferrocene Groups

Author: HongBiQiong
Tutor: YangFaFu
School: Fujian Normal University
Course: Organic Chemistry
Keywords: Calix [4 ] arene Ferrocene Coordinate Synthesis Cyclic voltammetry Supramolecular electrochemical recognition
CLC: O627.81
Type: Master's thesis
Year: 2010
Downloads: 27
Quote: 0
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Abstract


Calixarene is a class of more than one phenol unit formed by connecting via methylene cyclic oligomers , known as following the crown ether and cyclodextrin after the third generation of supramolecular host molecules . The calixarene is easy to a lot of preparation , has a unique three-dimensional cavity structure , can pack together identification of ions and molecules object , has aroused widespread concern in recent years in the field of host-guest chemistry . Further, since the upper and lower edges of the calixarene precursor is easy to carry out a variety of chemical modification , is often used as a the effective molecules platform to build a lot of supramolecular systems . In view of the the electrochemical recognition function calix by the the hydrocarbon body in supramolecular chemistry and materials chemistry research has theoretical significance and important applications in the field of ion transport , electrochemical molecular devices , chemical sensing and molecular switch 'value, the the paper carried out ferrocene - based electrochemical activity Cup [ 4 ] the aromatics a number of points receptor design , synthesis and supramolecular functional studies , innovative research results . The main contents are as follows : First, the paper reviews the recent redox-active calixarene receptor design, synthesis and supramolecular electrochemical recognition sensing progress . Second, the design and synthesis of calixarene - Cu ( I ) organic-inorganic hybrid supramolecular complexes , studies show that Cu complexes containing unpaired electrons , no single electronic structure of the complexes in the presence of Cu in the form of Cu ( I ) . Third, the design and synthesis of two novel containing ferrocenyl Cup [ 4 ] aryl hydrocarbon receptor , which ferrocene electrochemical activity center . Cyclic voltammetry and ultraviolet spectral studies show that the compounds of the series of metal cations and anions having a good electrochemical response to the effect of having a series of anion salts with certain effects . Fourth , the design and synthesis of chiral Cup containing the amino acid fragment [4] arene receptors, UV spectrum performance studies have shown that this compound has good coordination role on a series of metal cations . Especially Na, K, Ag, Zn2, Cd2 transition metal and an alkali metal ion with the ability to exhibit good .

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CLC: > Mathematical sciences and chemical > Chemistry > Organic Chemistry > Elements in organic compounds > Ⅷ of group elements, organic compounds > Iron organic compounds
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