Dissertation > Excellent graduate degree dissertation topics show

The Study of Synthesis and Application of the Low-yellowing and Hydrophilic Silicone Softener

Author: LiuJunHui
Tutor: ZhouXiangDong
School: Suzhou University
Course: Textile Chemistry and Dyeing and Finishing Engineering
Keywords: Amino silicone oil activity polyether bulk polymerization low-yellowing wash resistance
CLC: TS195.23
Type: Master's thesis
Year: 2011
Downloads: 135
Quote: 3
Read: Download Dissertation

Abstract


the fabric finished by Conventional amino silicone oil has good flexibility, smooth, flexible, comfortable and washable. However, the finishing of fabric,especially,chemical fiber and blended fabric, Poor moisture absorption, worn by the hot, taking the performance degradation and yellowing of the fabric is easier. The finished fabric by silicone polyether has good moisture absorption, anti-static performance, when wearing the fabric is easy to overcome with static electricity, dust, hot and shortcomings, but the softness and feel relatively poor. To solve the above problems, comprehensive amino silicone oil and the advantages and disadvantages of silicone polyether, The subject of the bulk polymerization method used, the end of the introduction of hydrogen silicone oil in the main chain amino group of polyether and Asia to prepare a low-yellowing hydrophilic silicone softener. Since fabric softener after finishing the ordinary, feel, and there is contradiction between the two hydrophilic, the subject of low-yellowing synthetic hydrophilic silicone softener, fabric handle and can be hydrophilic to ensure good premise, has greatly improved the fabric of the yellowing phenomenon.1. By bulk polymerization approach to hydrogen silicone oil, reactive polyether, and N, N-methylene bisacrylamide as raw materials and toluene as solvent, chloroplatinic acid - isopropanol as a catalyst in the main terminal hydrogen silicone oil The introduction of polyether chains and the amino group of Asia, was synthesized by a low-yellowing hydrophilic silicone softener emulsion.2. The configuration and properties of the low-yellowing and hydrophilic Silicone Softener were characterized by FTIR, TG-DTA, SEM, TEM, Zeta electric potential and particle size analysis.3. Experiments show that: reaction temperature 100℃, reaction time 10h, the amount of catalyst 0.5mg/kg, the material ratio of hydrogen silicone oil: reactive polyether: N, N-methylene bisacrylamide = 1.5:1: 1, the synthesis of low-yellowing hydrophilic silicone softener finishing fabric, the fabric can give a better hydrophilic, low yellowing and good softness and fullness of feeling, is also a good washing resistance.4. Low-yellowing hydrophilic silicone softener finishing polyester fabric softener optimum conditions for the amount of 100 g ? L-1, the curing temperature is 160℃, baking time is 3min.5. Fabric fabrics were treated with low-yellowing hydrophilic silicone softener and high ammonia values can be found after finishing amino silicone oil, low-yellowing hydrophilic amino silicone oil in ensuring the fabric on the basis of ultra-soft, anti-yellowing and pro-Water is also greatly improved, reaching all aspects of dyeing processing requirements.

Related Dissertations

  1. Aggregation of Initiator and Mechanism of Styrene Anionic Bulk Polymerization,O631.5
  2. Synthesis of PSt-b-PtBA Diblock Copolymer by Activator Generated by Electron Transfer Atom Transfer Radical Polymerization,O631.3
  3. The Comparison of Poly-α-Olefins between Bulk Polymerization and Solvent Polymerization of the Oil-soluble Drag Reducer and Research on Prepolymerization,TE869
  4. The continuous bulk Law PMMA resin polymerization process,TQ320.61
  5. Synthesis and Characterization for the Polyphosphazenes,O634.51
  6. Study of Atom Transfer Radical Polymerization of Methyl Methacrylate,TQ316.322
  7. Synthesis of R(MAA)3/PMMA Composite for X-Ray Sheilding and Study of Gel Glass,TQ171.7
  8. Study on the Effect of Drag Reduction Agent on the Oil’s Properties and the Drag Reduction Agent’s Continuous Production,TE869
  9. Syntheses, Properties and Recognition Mechanism of Molecularly Imprinted Micropheres and Nanofibers for Bisphenol A,O631.3
  10. Study on the Synthesis and Modification of Aqueous Polyurethane,TQ323.8
  11. A Study of Activator Generated by Electron Transfer Atom Transfer Radical Copolymerization of Fluorinated Acrylate Copolymer in Aqueous Media,O631.5
  12. Optimization of the Preparation of New Permeable Polyacrylic Resin and Its Performances Investigation,TQ325.1
  13. Study on Film Morphology, Surface Properties and Film Formation Mechanism of Amino Silicone Oils,TS195.23
  14. Three-Stage Polymerization Model for Free Radical Polymerization and Experimental Studies on the Polymerization of Potassium Acrylate,TQ316.322
  15. Bulk Ring-Opening Copolymerization of D4 with APAEDMS and Its Mathematic Simulation,TQ316.341
  16. The Synthesis of Low Dielectric Loss Cross-linking Polystyrene,TQ325.2
  17. Study on Kinetics of Polymerization of Styrene and It’s Copolymerization Action with Existence of Montmorillonite,TQ316.3
  18. The development of the acrylate liquid rubber,TQ333
  19. Research and development of new oil DRA polymer,TE869
  20. Study on the Catalytic Behaviors of β-diketone Ti、Zr in Ring-Opening Polymerization of Lactide,TQ316.341
  21. Preparation of Amino Silicon Oil Through Bulk Copolymerization,TQ264.1

CLC: > Industrial Technology > Light industry,handicrafts > Textile industry,dyeing and finishing industry > Dyeing and finishing industry > Finishing > Finishing with agent > Stiffening agents , softeners
© 2012 www.DissertationTopic.Net  Mobile