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Hydrothermal Synthesis and Research of New Indium Phosphate (Indium Phosphite)

Author: YiZhuo
Tutor: PangWenQin
School: Jilin University
Course: Inorganic Chemistry
Keywords: Indiumphosphate Indium phosphite Microporous Crystals Hydrothermal Synthesis
CLC: O614
Type: Master's thesis
Year: 2005
Downloads: 101
Quote: 3
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Abstract


In this thesis, the hydrothermal system, with novel microporous framework structure indiumphosphate Synthesis and characterization studies designed to further identify and indium phosphate microporous structure and composition of the diversity of compounds , while the microporous indium phosphite compound the synthesis is an exploratory study . In the In-H3PO4-amine-HF-H2O system , the use of triethylene diamine and N- methylpiperazine as the template , the synthesis of the fluorine ion system, the structure of the two novel microporous indium phosphate fluoride compound , the structure analysis showed that both have the same inorganic skeleton structure . Similar three-dimensional structure of indium phosphate fluoride synthesis studies show : indium phosphate fluoride fluoride ions on the skeleton plays a decisive role in the formation of organic amines as templating agent -oriented indiumphosphate different topologies ability compared with the main group of aluminum gallium weaker . In the In-H3PO3-amine-H2O system, instead of phosphorous acid as the phosphorus source , has been the first case of indium phosphite compound . In addition , the design of abalone ring structure comprising a combination reactor, its attempts to use it as combinatorial chemistry applied to the synthesis of inorganic microporous compound provides some ideas and experimental basis .

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CLC: > Mathematical sciences and chemical > Chemistry > Inorganic Chemistry > Metal elements and their compounds
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