Dissertation > Excellent graduate degree dissertation topics show

The dual-core phthalocyanine complexes were designed and synthesized and their catalytic properties of lithium / thionyl chloride battery

Author: WangJiFeng
Tutor: ZhaoJianShe
School: Northwestern University
Course: Inorganic Chemistry
Keywords: transition metal binuclear phthalocyanine compounds lithium/thionyl chloride battery catalytic mechanism
CLC: O646
Type: Master's thesis
Year: 2009
Downloads: 140
Quote: 1
Read: Download Dissertation

Abstract


In this dissertation, a series of binucler transition metal phthalocyanine complexes M2PC2. M2Pc2Hc, M2Nc2 （M = Mn（II）, Fe（II）, Co（II）, Ni（II）, Cu（II）） were synthesized by a solid phase fusion method, and others M2Pc2C, M2Pc2HcC, M2Pc2HnC（M = Mn（II）, Fe（II）, Co（II）, Ni（II）, Cu（II）） were synthesized by microwave process. All the phthalocyanine complexes were characterized by element analysis, UV-Vis absorption, Infrared spectra and TGA analysis. The effect on lithium/thionyl chloride battery （Li/SOCl2） had been investigated under constant resistance using phthalocyanines as electrocatalyst.The discharge voltage, discharge time and battery capacity, of Li/SOCl2 battery containing phthalocyanine are investigated, and the results show that the relationship of catalytic activity and center metal ion are as follows: Fe2+>Co2+>Mn2+>Ni2+>Cu2+. Because the redox reactions of phthalocyanine containing Mn（II）, Fe（II）, Co（II） relate to not only phthalocyanine ring ,but also metal ions; the others occur mainly in the phthalocyanine ring. The catalytic feature is confirmed by the cyclic voltammetry also.The catalytic activity of binuclear metal phthalocyanine is compared with that of mononuclear phthalocyanine. It is found that the conjugated system of phthalocyanines increased can improve their catalytic activity. A new perspective on the catalytic mechanism of the reduction of thionyl chloride by binuclear phthalocyanine compounds is brought forward. The catalytic activity is attributed to the adduct of phthalocyanine compounds and thionyl chloride.

Related Dissertations

  1. Study on the Synthesis of the Polypyrrole-Cobalt Oxides and Their Catalytic Behavior for the Electroreduction of H2O2,O643.32
  2. Theoretical Analysis of the Circular Dichroism Spectra of Transition Metal Schiff-Base Complexes,O641.4
  3. 2,6 - diaminopyridine organometallic compounds as precursors Synthesis and Characterization,O627
  4. Syntheses, Structures and Properties of Transition Metal Complexes Based on Pyridyl Ligands,O627.2
  5. Activation and Transformation of Carbodiimide by Lanthanide Tris(phenoxide)s,O627.3
  6. Synthesis、Structures and Characters of Coordination Polymers of Aromatic Carboxylic Acid,O631
  7. Direct Catalytic Conversion of Glucose into Low Carbon Glycols Over Transition Metal Carbide Catalysts,TQ223.162
  8. Studies about Complexes Based on Pyridine-2,4,6-tricarboxylic Acid,O621.13
  9. First Principle Calculations for the Lattice and Thermodynamics of FCC Metals,O469
  10. The Theoretical Foundation and Current Situation of the Research on Optical and Magnetic Properties of 3d Transition-metal Ions,O469
  11. Synthesis of Novel Oxazoline Ligands and Selective Oxidation of Alcohols,O626.2
  12. Synthesis and Hydrogen Storage Properties of Li-Mg-Al-H Complex Hydrides,TG139.7
  13. Fine Structures and Phase Transition Mechanism of Diamond/Fe-Based Metal Film Interface,TQ164
  14. Bromide phthalocyanine complexes Synthesis and catalytic properties of lithium / thionyl chloride battery,O621.1
  15. Micro reserve lithium battery research,TM912
  16. Spin- flip transition metals react with acetonitrile relativistic density functional theory study,O621.13
  17. DFT Study on the Mechanisms of Several Reactions Catalyzed by Transition Metal,O643.12
  18. Effect of Transition Metal Oxides and Chemical Bleaching Process on the Whiteness of Kaolins,TD985
  19. A new three teeth secondary amine ligands and their complexes Synthesis, Characterization and Properties,O641.4
  20. Nickel, copper -catalyzed coupling reagents heterocyclic boronic acid as direct arylation,TQ203.2

CLC: > Mathematical sciences and chemical > Chemistry > Physical Chemistry ( theoretical chemistry ),chemical physics > Electrochemical,electrolytic,magnetic,chemical
© 2012 www.DissertationTopic.Net  Mobile