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Seven coordination compounds are synthesized by employing （3,5-dinitrobenzoic acid, 4-Chlorophenoxyacetic acid, 4-Nitrophenoxyacetic acid） and associated ligands（imidazole, N,N′-（1,4-butanediyl）bis（imidazole）） as building block, combining with metal ions under solution reaction conditions. The crystal structures are determined by X-ray single diffraction and characterized by element analysis, IR, TGA-DSC, Magnetic measurements. The formulas of the compounds are as follows: {[Ni（DNBC）2（Im）（H2O）]·0.25H2O}（1） [Zn（DNBC）2（Im）2]（2） [Cu（DNBC）2（Im）（H2O）]（3） [Co1.5（DNBC）4（Im）（CH3OH）（H2O）2]（4） [C28H34Ag2ClN9O12]（5） [C25H21CoN4.50O18]（6） [Cu（p-ClBA）2（Im）2]（7）The complex1 crystallized crystallizes in the Orthorhombic system with space group- Pbca, a = 1.5022（6） nm, b = 1.5146（6） nm, c = 1.9269（7） nm, V = 4.384（3） nm3, Z = 8, F（000） = 2320. The crystal structure shows the complex1 has a 1D chain networks,w- here each Ni（II） is in 4O+N coordination modes, each five-coordinated Ni（II） ions form a distorted square-pyramidal geometry, oxygen atoms（O12） occupy axial center positions with Ni1-O12=0.2607nm. The complex2 possesses tridimensional netlike supramolecular structure which is formed by intermolecular hydrogen bonding and V- an der Waals force, where each Zn （II） is in 2O+2N coordination modes, each four c- oordinated Zn （II） ions form a distorted tetrahedral geometry. The complex3 has a 1D zigzag chain networks, where each Cu （II） is in 4O+N coordination modes, and each five coordinated Cu （II） ions form a distorted square-pyramidal geometry. The comp- lex4 crystallizes in the monoclinic system with space group P2（1）/n, a = 1.20876（7） n m, b = 2.63287（16） nm, c = 1.36466（9） nm, V = 4.3045（5）nm3, Z = 4, F（000） = 2166, the adjacent Co…Co distance of 0.3587nm. Complex 4 possesses 1D zigzag chain c- omposed by Co（II） and byμ-OH2, while triple-clear of octahedral Co（II） bridged by μ-OH2 further connected through the hydrogen bonding to adjacent triple-clear Co（II）. Thus, the aggregation of the coordination units through O–H…O hydrogen bonds, re- sults in the formation of channels, which are occupied by imidazole molecules and m- ethanol molecules. Magnetic measurements of complex 4 indicate antiferromagnetic interactions between adjacent Co （II） ions within the trimer. The complex5 crystal- lizes in the Triclinic system with space group P-1, a = 0.91967（10） nm, b = 1.21032（13） nm, c = 1.7762（2） nm. The crystal structure shows the complex has a 1D chain networks, where each Ag is in N+N coordination modes, each two-coordinated Ag ions form a chain networks geometry. The complex6 crystallizes in the Triclinic s- ystem with space group P-1, a = 3.7673（16） nm, b = 1.0000（4） nm,c = 1.7892（7） nm. The crystal structure shows the complex has a 1D chain networks, where each Co is in 5O+N coordination modes, each five-coordinated Co ions form a chain networks geo- metry. The complex7 crystallizes in the Triclinic system with space group P-1, a = 1.01598（15） nm, b =1.05135（15） nm, c = 1.05549（15） nm,α= 101.649（8）°,β= 96.998（8）°,γ= 102.394（8）°, V = 1.0623（3）nm3, Z = 2, F（000） = 514. The compl- ex7 formed distorted square-pyramidal through coordination two O of two 4-Chlor- obenzoic acid （p-ClBA） and two N of two imidazole （Im） molecule. It further cons- tructed 2D supramolecular structure by hydrogen bonds,π–πinteraction and electr- ostatic pull.
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