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Study on Structure and Properties of Flame Retardant ABS
Author: ChenGuoChang
Tutor: LiuGuangZuo
School: Qingdao University of Science and Technology
Course: Materials processing
Keywords: ABS CPE Flame retardants Heat stabilizers Toughening DBDPE Encapsulated red phosphorus MCA
CLC: TB332
Type: Master's thesis
Year: 2006
Downloads: 527
Quote: 0
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Abstract
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Of this research project is divided into three parts : the thermal stability of the CPE , decabromodiphenyl ethane flame retardant ABS development , and the development of halogen - free flame retardant ABS , focuses on the structure and properties of flame retardant ABS , and its resistance ignition mechanism was discussed . Congo red experiments show that the hydrotalcite and dibutyltin laurate and have good thermal stability of the CPE . Combined flame retardants DBDPE / Sb 2 O 3 , ABS retardant properties of the composite to improve the impact strength decreased . When the amount of 14% , ABS flame retardant properties of the composite material to achieve UL94 V-0 level, the impact strength is reduced to pure ABS 130J / m 35J / m, a 73.1% decrease . DBDPE / Sb 2 O 3 is a typical gas flame retardant mechanism . The Add CPE after the ABS composite materials impact strength is greatly increased, when an amount of 28wt% , the impact strength of 130J / m of the pure ABS to 230J / m, 76.9 % . The electron micrograph shows the spherical structure of the dispersed phase in the impact fracture of the CPE / ABS blend elongation deformation occurs , the amplitude of deformation is greater than 100% . Stretching , CPE particles due to being pulled to its equatorial plane position subjected to a large compressive stress and generating elongation more energy leaving the toughness of the blend can be improved , and thus in the force absorbed . The experiments show that there is a synergistic effect between encapsulated red phosphorus and MCA . When the amount thereof is 20wt% , the flame retardant properties of the composite material to reach UL -94 V -0 level . For ABS , RP / MCA is also a good smoke suppressant . The residue after combustion of the sample morphology difference . ABS / DBDPE / Sb 2 O 3 composites , ABS / bisphenol A phosphorus flame retardant composites , after the burning of the ABS / of MCA composites in tinfoil basically There is no money residue , main Description DBDPE / Sb 2 O 3 , bisphenol A phosphorus flame retardant and MCA is gas-phase flame retardant . ABS / red phosphorus coated ABS / aluminum hydroxide , and after the combustion of the ABS / magnesium hydroxide to form a thick and continuous carbon layer , and with the increase in density of the flame retardant increasing amount of carbon layer described encapsulated red phosphorus , aluminum hydroxide, magnesium hydroxide in a solid phase flame retardant based.
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CLC: > Industrial Technology > General industrial technology > Materials science and engineering > Composite materials > Non-metallic composite materials
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