Dissertation > Excellent graduate degree dissertation topics show

Electrochemical Synthesis and Characterization of Transition Metal Cu(Ⅱ)、Zn(Ⅱ)、Ni(Ⅱ) Complexes with Amino Acid

Author: ZhangXiuMei
Tutor: ZuoDaoZuo
School: Anhui Normal University
Course: Organic Chemistry
Keywords: amino acid Transition metal complexes Electrochemical synthesis “Sacrificial”anodes method Salicylidene amino acid Schiff base tosyl- L-isoleucine
CLC: O641.4
Type: Master's thesis
Year: 2006
Downloads: 393
Quote: 1
Read: Download Dissertation

Abstract


The transition metal organic complex exhibit function of the light, the electricity, the magnetism, the catalysis, the biochemistry characteristic and so on.The electrosynthesis of metal complexes use pure metal as sacrificing anode and inertia electrode or metal electrode as cathode.Current was passed through the electrolyte solution with supporting electro-condutive additives,Metallic anode was dissolved and reducing reaction occurred on cathode. The main advantage of electrochemical syntheses is that the reaction takes place in one step with high selective , high purity , non-pollution and so on. So the result is especially interesting since they show the possibility of wider application of electrosynthesis in the modern coordination chemistry.Electrosynthesis method is a green chemistry method with sustainable development. The development of electrochemical syntheses in syntheses of transition organometallics was very quick in recent years. In this paper,the main study obtained are as follows:Part one: Electrochemical Synthesis and Characterization of Transition Metal Cu(II)、Zn(II)、Ni(II) Complexes with a Schiff Base Ligand from Salicylidene and L-isoleucine.The direct electrosynthesis of Cu(II)、Zn(II) and Ni(II) complexes of salicylideneamino acid was accomplished by electrochemical dissolution of sacrificial metallic anodes in an acetonitrile solution of the ligand

Related Dissertations

  1. Eiectrosynthesis of Three Conducting Polymers with Carboxyl Group and Preparation of DNA Sensor Based on Poly(Indole-6-Carboxylic Acid) Films,TP212.2
  2. Research on Electrochemical Synthesis and Application of Conductive Polyaniline,O633.21
  3. Basic Research for Electrocatalysis Synthesis Process of Chromic Anhydride in Integrated Technology of Clean Chromic Salts Production,TQ26
  4. Electrochemical Synthesis of Diamond and Diamond-like Materials under Ambient Temperature and Pressure,TQ164
  5. Investigation on the Electrochemical Utilization of Carbon Dioxide,O621.3
  6. Research on Elcetrochemical Synthesis and Anticorrosion Property of Polyaniline Composite Films,O631.3
  7. Controlled Synthesis and Characterization of Noble Metal Nanoparticles,TB383.1
  8. Synthesis and Characters of Hydroxyapatite Coating by Electrochemical Methods,O611.4
  9. Basic Research and Thermodynamic of Relative Solution for Direct Electrosynthesis Process of p-Aminophenol,TQ164
  10. Study on Preparation of Metal Oxide Semiconductor Materials by Electrochemical Methods,TN304.21
  11. Electrochemical Synthesis and Characterization of Nanometer Scale Ceria, Lanthana and Neodymium Rare Earth Oxides,O614.33
  12. Synthesis and application of ionic liquid conductive polyaniline,O633.21
  13. The conductive polymer morphology law applied research,O631
  14. Synthesis and Property Study of Alternating Conjugated Polymers Constituted of Varieties of Aromatic Rings and Heterocycle by Using Oxidative Polymerization Method,O631.3
  15. Preliminary Studies on Electrosynthesis Chromic Anhydride from Sidium Chromate,O611.3
  16. Electrochemical Synthesis of Sodium Peroxycarbonate with Diamond Film,X703
  17. Metallization Iridium (Ⅲ) Complexes and their luminescent properties of the rigid ring,O641.4
  18. Theoretical Analysis of the Circular Dichroism Spectra of Transition Metal Schiff-Base Complexes,O641.4
  19. A Density Functional Theory Study for Wn C0,± （n=1-6） Clusters,O641.1
  20. A Study for Structure and Properties of OsnN0, ± （n=1-6） Clusters,O641.1
  21. Synthesis and Characterization of Metal Complexes Supported by S/N Ligands and Their Optical and Electrical Properties,O641.4

CLC: > Mathematical sciences and chemical > Chemistry > Physical Chemistry ( theoretical chemistry ),chemical physics > Structural Chemistry > Complex chemistry ( coordination chemistry )
© 2012 www.DissertationTopic.Net  Mobile